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- Direct synthesis of 2-oxo-acetamidines from methyl ketones . . .
In conclusion, the copper-catalyzed oxidative amidination of methyl ketones with aromatic amines and DMF has been developed Acyclic 2-oxo-acetamidines could be obtained with moderate to good yields This protocol features with acyclic amidines formation using DMF and aromatic amines as two di erent nitrogen sources Further investigations on
- Insights into Recent Nickel-Catalyzed Reductive and Redox C C . . .
CONSPECTUS: Transition metal-catalyzed reductive cross-coupling of two carbon electrophiles, also known as cross-electrophile coupling (XEC), has transformed the landscape of C−C coupling chemistry Nickel catalysts, in particular, have demonstrated exceptional performance in facilitating XEC reactions, allowing for diverse elegant transformations by employ-ing various electrophiles to forge
- Mechanistic Aspects of the Palladium-Catalyzed Suzuki-Miyaura . . .
Mechanistic Aspects of the Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reaction Massimo C D’Alterio,[a, b] Èric Casals-Cruañas,[a] Nikolaos V Tzouras,[c]Giovanni Talarico,[b] Steven P Nolan,*[c] and Albert Poater*[a]
- Intermolecular Aerobic Oxidative Allylic Amination of Simple . . .
ABSTRACT Intermolecular aerobic oxidative allylic amination of simple alkyl alkenes with simple amines such as diphenylamine was induced by a Pd(OCOCF3)2 NPMoV catalytic system, leading to the corresponding (E)-allylamines in good yield and selectivity through the formation of (η3-allyl)palladium(II) trifluoroacetate species as a possible key intermediate
- ja5b13519 1. . 4 - UNL
ABSTRACT: The catalytic dehydrogenative coupling of alcohols and amines to form aldimines represents an environmentally benign methodology in organic chem-istry This has been accomplished in recent years mainly with precious-metal-based catalysts We present the dehydrogenative coupling of alcohols and amines to form imines and H2 that is catalyzed, for the first time, by a complex of the
- Transition metalâ catalyzed alkyl-alkyl bond formation . . .
Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry Fu* Junwon Choi and Gregory C
- PII: 0009-2509(93)80274-T - University of California, Berkeley
Oxidative coupling offers a potential route for the anedehydrodimertition (pyrolysis) reactions by kin-direct conversion of light alkanes (C,X,) to more eticcoupling of the dehydrogenation and water useful products
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