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Virial expansion of real gas equation and volume work In the second part of the problem, it asks me to find the virial expansion of the first given equation (Dieterici equation) of p to quantify the difference of the volume work between an ideal gas vs a Dieterici gas
How does one experimentally determine virial coefficients? The Virial expansion is a systematic correction to the ideal gas law which takes the form of an expansion around the number density, $\\rho$, of the gas in question It looks like this: $$\\frac{p}{k
physical chemistry - Virial equation of state - Taylor expansion . . . I had misunderstood (probably you too) based on what I read in some site or videos The ideal gas equation is obtained from the virial expansion and not the opposite McQuarrie, Donald A The Virial Equation of State from the Grand Partition Function, Section 12-1, p 224, in Statistical Mechanics, ISBN 06-044366-9
physical chemistry - Finding the Boyle temperature for Dieterici gas . . . I think there is some mathematical trick to write this equation of state as a virial expansion with coefficients that depend only on temperature I couldn't find any satisfactory information about it on the Internet or figure out how to express \eqref {eq1} for the appropriate virial expansion
physical chemistry - Generate fit of virial expansion to osmotic . . . Yes, if you know how to use software such as Mathematica or Python to perform a least-squares fit then you can fit a polynomial in c to the data to extract virial expansion coefficients Unfortunately that is not a chemistry problem, that is a programming problem
physical chemistry - Work done in reversible isothermal expansion . . . This process is known as an isothermal expansion - isothermal because the temperature remains constant throughout - and expansion because volume is increased In thermodynamics it is very important to note which variables are held constant, because then that lets you decide which formula is appropriate to use, or how to derive such formulae)
Newest isotherm Questions - Chemistry Stack Exchange Virial expansion of real gas equation and volume work Hi I am currently working on a thermodynamics problem, and it asks me to first find the volume work done on a gas that behaves like the simplified Dieterici equation (see below) predicts on isothermal